Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**

نویسندگان

  • Yahui Wang
  • Michael E Muratore
  • Zhouting Rong
  • Antonio M Echavarren
چکیده

7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C1 component of the cycloaddition.

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عنوان ژورنال:

دوره 53  شماره 

صفحات  -

تاریخ انتشار 2014